کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1335788 1500286 2013 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Manganese(III) porphyrin supported on multi-wall carbon nanotubes: A highly efficient and reusable biomimetic catalyst for oxidative decarboxylation of α-arylcarboxylic acids and oxidation of alkanes with sodium periodate
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Manganese(III) porphyrin supported on multi-wall carbon nanotubes: A highly efficient and reusable biomimetic catalyst for oxidative decarboxylation of α-arylcarboxylic acids and oxidation of alkanes with sodium periodate
چکیده انگلیسی

In the present work, the highly efficient oxidative decarboxylation of carboxylic acids and also the oxidation of alkanes with sodium periodate catalyzed by tetrakis(p-aminophenyl)porphyrinatomanganese(III) chloride, [Mn(TNH2PP)Cl], supported on functionalized multi-wall carbon nanotubes, MWCNT, is reported. The catalyst, [Mn(TNH2PP)Cl@MWCNT], was used as an efficient and heterogeneous catalyst for hydroxylation of alkenes with NaIO4 at room temperature, in the presence of imidazole as an axial ligand. Also, in this system, carboxylic acids were converted to their corresponding carbonyl compounds. This heterogenized catalyst could be reused several times without significant loss of its catalytic activity.

Highly efficient oxidative decarboxylation of carboxylic acids and also oxidation of alkanes with sodium periodate catalyzed by tetrakis(p-aminophenyl)porphyrinatomanganese(III) chloride, [Mn(TNH2PP)Cl], supported on functionalized multi-wall carbon nanotubes, MWCNT, is reported. This heterogenized catalyst could be reused several times without significant loss of its catalytic activity.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 53, 10 April 2013, Pages 15–19
نویسندگان
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