کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1335849 | 979556 | 2016 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and characterization of Ru2(η2-DmAniF)2(μ-DmAniF)2(μ-OAc)(μ-O)
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A new diruthenium compound, Ru2(η2-DmAniF)2(μ-DmAniF)2(OAc)(O) (1), where DmAniF is N,N′-di(m-methoxyphenyl)formamidinate, was isolated as a secondary product from the reaction between Ru2(DmAniF)3(OAc)Cl and K2CO3, and its formulation was established using both single crystal X-ray diffraction and high resolution mass-spectrometry techniques. Compound 1 has an S = 3/2 ground state, and exhibits an unusually large zero-field splitting (D = 308 cm−1) as revealed by the measurement of temperature dependent magnetism.
A new diruthenium compound Ru2(η2-DmAniF)2(μ-DmAniF)2(OAc)(O) was isolated and interesting structural and magnetic properties were revealed.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 103, Part A, 8 January 2016, Pages 126–130
Journal: Polyhedron - Volume 103, Part A, 8 January 2016, Pages 126–130
نویسندگان
Stacey R. Opperwall, Bin Liu, Alice L. Pilo, Zhi Cao, Phillip E. Fanwick, Tong Ren,