کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1335911 | 1500239 | 2015 | 11 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Aminopyridine complexes of Cr(III) basic carboxylates as potential polymer precursors: Synthesis, characterization, and crystal structure of [Cr3O(propionate)6(X-aminopyridine)3]+ (X = 3 or 4) Aminopyridine complexes of Cr(III) basic carboxylates as potential polymer precursors: Synthesis, characterization, and crystal structure of [Cr3O(propionate)6(X-aminopyridine)3]+ (X = 3 or 4)](/preview/png/1335911.png)
Synthesizing one- and two-dimensional arrays of trinuclear chromium(III) basic carboxylate complexes could give rise to new materials with interesting magnetic properties. Trinuclear chromium(III) basic carboxylate complexes where a substituted pyridine ligand could be used to link the trinuclear complexes together could serve as avenue to the synthesis of such arrays. Toward this end, the syntheses, crystal structures, and properties of [Cr3O(propionate)6(4-aminopyridine)3]+ and [Cr3O(propionate)6(3-aminopyridine)3]+ are presented.
The synthesis and characterization including X-ray crystal structures of chromium(III) basic carboxylate assemblies with terminal amino pyridine ligands as potential building blocks for polymers are described.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 100, 4 November 2015, Pages 17–27