کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1336142 | 1500249 | 2015 | 5 صفحه PDF | دانلود رایگان |
New dinitrosyl iron complexes of binuclear structure [Fe2(μ-SCHMe2)2(NO)4] and [Fe2(μ-SCHPh2)2(NO)4] were first synthesized employing new method from Fe(CO)5, corresponding thiol, and EtONO. Complexes structures were determined by XRD technique. DFT calculations were performed to probe the cis-conformer structures in gas and solution phases. NO donor ability of the complex with isopropyl thiolate ligand was studied.
Complexes [Fe2(μ-SCHMe2)2(NO)4], [Fe2(μ-SCHPh2)2(NO)4] were first synthesized employing new method from Fe(CO)5, EtONO, and corresponding thiol; their structures were determined. NO donor ability of the [Fe2(μ-SCHMe2)2(NO)4] complex was studied. DFT calculations were performed to probe the cis-conformer structures in gas and solution phases.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 90, 18 April 2015, Pages 197–201