کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1336503 | 1500269 | 2014 | 8 صفحه PDF | دانلود رایگان |
The combination of iridium with trimethylphosphine ligands yields very electron rich iridium compounds that are active for terminal alkyne dimerization chemistry as well as the addition of carboxylic acids to alkynes. The structures, catalytic and stoichiometric chemistry of some iridium tris-trimethlyphosphine compounds with benzoate ligands are detailed in this paper. The roles that these compounds may play in the catalytic cycles involved in the dimerization of terminal alkynes and the addition of benzoic acid to terminal alkynes are examined and possible mechanisms for these catalytic reactions are proposed.
A system with phenylacetylene and benzoic acid with an iridium catalyst produces products from addition of phenylacetylene to phenylacetylene, benzoic acid to phenylacetylene and benzoic acid to the phenylacetylene/phenylacetylene product. The compounds whose structures are shown were metal complexes isolated from this reaction system.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 70, 9 March 2014, Pages 125–132