کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1336613 1500271 2014 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and characterization of sodium polymeric complexes containing carbanionic 3,5-dicyano-6-dicyanomethyl-(ferrocenyl)pyridine and 2-ferroceny(tetracyano)propene ligands
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and characterization of sodium polymeric complexes containing carbanionic 3,5-dicyano-6-dicyanomethyl-(ferrocenyl)pyridine and 2-ferroceny(tetracyano)propene ligands
چکیده انگلیسی

Novel Na+ polymeric complexes, {[Na+(2-ferrocenyl(tetracyano)propenyl)−L]∞ and [Na+(2-amino-3,5-dicyano-4-ferrocenyl-6-pyridyl-dicyanomethyl)−L]∞, where L = methanol, acetonitrile, dimethylformamide, acetone, ethyl acetate} were prepared by reactions of 2-cyano-3-ferrocenylacrylonitrile with malononitrile (∼1:3) in a MeOH/H2O medium in the presence of Na2CO3. The new complexes were characterized by elemental analysis, spectroscopy, and single-crystal X-ray diffraction analysis.

Novel Na+ polymeric complexes, {[Na+(2-ferroceny(tetracyano)propenyl)−L]∞ and [Na+(2-amino-3,5-dicyano-4-ferrocenyl-6-pyridyl-dicyanomethyl)−L]∞, where L = methanol, acetonitrile, dimethylformamide, acetone, ethyl acetate} were prepared by reactions of 2-cyano-3-ferrocenylacrylonitrile with malononitrile. The new complexes were characterized by elemental analysis, spectroscopy, and single-crystal X-ray diffraction analysis.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 68, 28 January 2014, Pages 272–278
نویسندگان
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