Dimeric and polymeric silver(I) saccharinato complexes of two bis(pyridine) ligands: Synthesis, structural, spectroscopic, fluorescent and thermal properties

Two new silver(I) complexes [Ag2(sac)2(bpeh)] (1) and [Ag(sac)(bpma)]n (2) have been synthesized and structurally characterized. Complex 1 shows a binuclear composition, while 2 is a one-dimensional helical polymer. Both complexes show conformational chirality.