کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1336953 1500287 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Novel 3D lanthanum oxalate metal-organic-framework: Synthetic, structural, luminescence and adsorption properties
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Novel 3D lanthanum oxalate metal-organic-framework: Synthetic, structural, luminescence and adsorption properties
چکیده انگلیسی

The hydrothermal reaction of La(NO3)3 with 2-pyrimidinecarbonitrile in water yields a 3D metal-organic coordination framework [La2(ox)3(H2ox)(H2O)2](H2O)8 (1) (ox = oxalate). This compound has channels with hosted water molecules inside and shows an intense photoluminescence emission at room temperature in the solid state. Due to the great channels that this compound possesses we have analyzed the experimental and simulated adsorption properties. This is one of the few examples of three-dimensional lanthanum polymers based only on oxalate ligand.

The hydrothermal reaction of La(NO3)3 with 2-pyrimidinecarbonitrile in water yields a 3D metal-organic coordination framework [La2(ox)3(H2ox)(H2O)2](H2O)8 (ox = oxalate). This compound has channels with hosted water molecules inside and shows an intense photoluminescence emission at room temperature in the solid state. Due to the great channels that this compound possesses we have analyzed the experimental and simulated adsorption properties. This is one of the few examples of three-dimensional lanthanum polymers based only on oxalate ligand.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 52, 22 March 2013, Pages 315–320
نویسندگان
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