کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1337354 | 1500252 | 2015 | 13 صفحه PDF | دانلود رایگان |
The molecular structures of several related cis-[κ2-SS-(L)MHal2] compounds 1, 1·DMSO, 2, 2·H2O, 3·DMSO, 4 and 5 where L = HOCH2Ph-S-CH2-CH2-S-PhCH2OH, M = Pd or Pt, and Hal = Cl or Br or I, were analyzed by single crystal X-ray diffraction analyses. In all complexes, the presence of intramolecular C–H⋯M (M = Pd or Pt) interactions with distance values of 2.687–2.914 Å was established. In solid state both syn- or anti-conformers exist; this suggests that one or two ortho-hydrogen atoms on the phenyl rings are close to the metal. Furthermore, the existence of these weak interactions induce a significant effect on the geometry adopted by the metal center. The crystal structures show a wide variety of intermolecular noncovalent bonding such as hydrogen bonds, M⋯M contacts, π-π, C–H⋯π and Hal⋯π interactions. For all the complexes, the structural analysis performed by Density Functional Theory (DFT) is in good agreement with parametric data obtained from X-ray measurements. Topological analyses of the electron density function [ρ(r)], which have been performed according to Bader’s Atoms in Molecules theory, reveal bond critical points relating the metal atom with aromatic ortho-hydrogen atoms. Laplacian ∇2ρ(r) and density ρ(r) values indicate formation of the weak anagostic C–H⋯M interactions.
Monometallic cis-[κ2-SS-(HOCH2Ph-S-CH2-CH2-S-PhCH2OH)MHal2] [M = PdII, PtII and Hal = Cl, Br, I] complexes can present both syn- or anti-conformers. The syn-confomers show one C–H⋯M interaction while anti-conformers present two C–H⋯M interactions.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 87, 17 February 2015, Pages 181–193