کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1337411 | 979628 | 2009 | 7 صفحه PDF | دانلود رایگان |
The reaction of RhCl3·3H2O with the ligand L = 2-(2′-pyridyl)quinoxaline (pqo) in a 1:2 molar ratio formed the mononuclear complex cis-[RhL2Cl2]Cl (1), which has been characterized by elemental analysis, FT-IR, FT-Raman, 1H, 13C NMR, electronic absorption spectroscopy and by electrospray mass spectrometry. The molecular structure of 1 (needle like and prismatic polymorphs) in the crystal has been elucidated by single-crystal X-ray diffraction, revealing a bidentate behavior of L, while the geometry around the Rh(III) atom is that of a distorted octahedron.. Preliminary biological tests revealed that this compound inhibited PAF-induced rabbit platelet aggregation.
The mononuclear Rh(III) complex, cis-[RhL2Cl2]Cl (1) where L = 2-(2′-pyridyl) quinoxaline (pqo) has been prepared and fully characterized. The molecular structure in the crystal of complex 1 is also described, revealing a distorted octahedral geometry. The effect of this compound on PAF-induced rabbit platelet aggregation was investigated.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 28, Issue 15, 13 October 2009, Pages 3310–3316