The reaction of thiophenoxide with amino-substituted chloro-cyclotriphosphazenes

Six products were synthesised from the reaction of primary or secondary amino-substituted cyclotriphosphazenes with thiophenol. The structures of these compounds were characterised by elemental analysis and MS, 1H and 31P NMR spectroscopies. Molecular and crystal structures of N3P3Cl4(NHPh)(SPh) (5) and N3P3Cl4(NC4H8)(SPh) (13) were investigated by X-ray crystallography.