کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1337567 | 979633 | 2009 | 7 صفحه PDF | دانلود رایگان |
Five coordination polymers, namely [Cd(L3)2]·H2O (1), [Zn(L3)2] (2), [Co(L3)2] (3), [Ni(L3)2] (4) and [Cu2(L3)2]·3H2O (5), where L3 = 3,5-bis(pyridin-3-ylmethoxy)benzoic acid, have been synthesized under hydrothermal conditions. Their structures have been determined by single-crystal X-ray diffraction analyses and further characterized by elemental analyses, IR spectra, and thermogravimetric (TG) analyses. Compound 1 is a binodal (3,4)-connected net with (63)(66) topology. Compounds 2–4 are isostructural and described by the uninodal (4,4)-connected net with (44 · 62) Schläfli symbol. The structure of 5 is a 2D binodal (6,3) net. In addition, the luminescent properties of compounds 1 and 2 have been studied in the solid state at room temperature.
Five coordination polymers, [Cd(L3)2]·H2O (1), [Zn(L3)2] (2), [Co(L3)2] (3), [Ni(L3)2] (4) and [Cu2(L3)2]·3H2O (5), where L3 = 3,5-bis(pyridin-3-ylmethoxy)benzoic acid, have been synthesized under hydrothermal conditions. 1 is a (3,4)-connected net with (63)(66) topology. 2–4 are isostructural and described by the (44 · 62) topology. The structure of 5 is a 2D binodal (6,3) net.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 28, Issue 14, 23 September 2009, Pages 3155–3161