کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1337612 | 979637 | 2012 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and structural characterization of cobalt(II) and copper(II) complexes with N,N-disubstituted-N′-acylthioureas Synthesis and structural characterization of cobalt(II) and copper(II) complexes with N,N-disubstituted-N′-acylthioureas](/preview/png/1337612.png)
A new complexes of Co(II) and Cu(II) with N,N-disubstituted-N′-acylthioureas have been prepared and characterized by elemental analysis, and spectroscopic techniques. The structure of N,N-diethyl-N′-furoylthiourea and Co(II) complexes with N,N-diethyl-N′-furoyl- and N,N-diethyl-N′-benzoylthiourea were determined by X-ray crystallography. The structural data reveal that the acylthiourea moiety adopts a cis conformation in the crystal and the complexes show a slightly distorted square-planar geometry.
A series of Co(II) and Cu(II) complexes with N,N-disubstituted-N′-acylthioureas have been synthesized and characterized. The structure of N,N-diethyl-N′-furoylthiourea and Co(II) complexes with N,N-diethyl-N-furoyl- and N′-benzoylthiourea were determined by X-ray difraction.Figure optionsDownload as PowerPoint slideHighlights
► Synthesis and characterization of new Cu(II) and Co(II)-acylthiourea complexes.
► X-ray structure of Co(II) complexes with N,N-diethyl-N-furoyl- and N,N-diethyl-N′-benzoylthiourea.
► The complexes show a slightly distorted square–planar geometry.
Journal: Polyhedron - Volume 36, Issue 1, 4 April 2012, Pages 133–140