کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1337698 | 1500260 | 2014 | 9 صفحه PDF | دانلود رایگان |
The reaction of the multidentate ligand N-(2-(aryldiazenyl)phenyl)picolinamide, HL (3a, 3b and 3c) [HL is ArN = NC6H4NHC(O)Py, where Ar is C6H5 for HL1 (3a), p-MeC6H4 for HL2 (3b) or p-ClC6H4 for HL3 (3c), and Py stands for pyridyl], with Cu(CH3COO)2·H2O and Na2PdCl4 separately afforded the complexes [(L)2Cu] (4a, 4b and 4c) and [(L)PdCl] (5a, 5b and 5c) respectively, where the deprotonated ligand L− binds copper(II) and palladium(II) in a tridentate (N,N,N) fashion. X-ray structures of [(L3)2Cu] (4c) and [(L1)PdCl] (5a) were determined to confirm the molecular structures. The newly synthesized complex 4a exhibits catalytic activity toward the oxidation of alcohols to the corresponding carbonyl compounds and oxidation of organic thioethers to sulfoxide and sulfone, whereas the complex 5a is an active catalyst for Suzuki and Heck reactions.
Copper(II) and palladium(II) complexes of azo-amide ligands have been prepared and characterized unequivocally. The copper complexes are active catalysts for the oxidation of alcohols to the corresponding carbonyl compounds or the oxidation of organic thioethers to sulfoxides and sulfones, whereas the palladium complexes are good catalysts for Suzuki-cross-coupling and Heck reactions.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 79, 5 September 2014, Pages 43–51