کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1338012 | 979657 | 2007 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Iron(III) mixed-ligand complexes: Synthesis, characterization and crystal structure determination of iron(III) hetero-ligand complexes containing 1,10-phenanthroline, 2,2′-bipyridine, chloride and dimethyl sulfoxide, [Fe(phen)Cl3(DMSO)] and [Fe(bipy)Cl3(D Iron(III) mixed-ligand complexes: Synthesis, characterization and crystal structure determination of iron(III) hetero-ligand complexes containing 1,10-phenanthroline, 2,2′-bipyridine, chloride and dimethyl sulfoxide, [Fe(phen)Cl3(DMSO)] and [Fe(bipy)Cl3(D](/preview/png/1338012.png)
Treatment of [Fe(bipy)Cl4][bipy · H] (1) and [Fe(phen)Cl4][phen · H] (3) (where bipy is 2,2′-bipyridine and phen is 1,10-phenanthroline) with dimethyl sulfoxide in methanolic solution produced [Fe(bipy)Cl3(DMSO)] (2) and [Fe(phen)Cl3(DMSO)] (4) (where DMSO is dimethyl sulfoxide), respectively. The resulting complexes were characterized by elemental analysis, IR, UV–Vis and 1H NMR spectroscopies and by the X-ray diffraction method. These complexes are high spin with a spin multiplicity of 6.
[Fe(bipy)Cl3(DMSO)] and [Fe(phen)Cl3(DMSO)] complexes (where bipy is 2,2′-bipyridine, phen is 1,10-phenanthroline and DMSO is dimethyl sulfoxide) were prepared and characterized by elemental analysis, IR, UV–Vis and 1H NMR spectroscopies and by the X-ray diffraction method.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 26, Issue 17, 30 October 2007, Pages 4908–4914