کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1338262 | 1500282 | 2013 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Functionalized bipyridyl rhodium complex capable of electrode attachment for regeneration of NADH
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Functionalized bipyridyl rhodium complex capable of electrode attachment for regeneration of NADH Functionalized bipyridyl rhodium complex capable of electrode attachment for regeneration of NADH](/preview/png/1338262.png)
چکیده انگلیسی
A Rh(III) complex having a functionalized bpy-OH ligand that is potentially linkable to electrode surfaces was synthesized and fully characterized. The hydrido complex, which could be generated either electrochemically by cathodic reduction of the [η5-Cp∗Rh(bpy-OH)Cl]Cl complex at −771 mV (versus Ag/AgCl) or chemically with formate, transformed NAD+ efficiently into NADH with a TOF = 710 at 60 °C.
A rhodium complex with free hydroxyl groups was synthesized and well characterized by single crystal X-ray analysis. Indirect electrochemical and chemical methods of regeneration of NADH are presented.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 57, 2 July 2013, Pages 52–56
Journal: Polyhedron - Volume 57, 2 July 2013, Pages 52–56
نویسندگان
Dharmalingam Sivanesan, Sungho Yoon,