کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1338264 | 1500282 | 2013 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The synthesis and characterization of a group of transition metal octabutoxynaphthalocyanines and the absorption and emission properties of the Co, Rh, Ir, Ni, Pd and Pt members of this group
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The synthesis and photophysical properties of new metallo-octabutoxynaphthalocyanines with Rh(III), Ir(III), and Pt(II) are reported. Various metals were inserted into the metal-free octabutoxynaphthalocyanine and the resultant metal complexes were fully characterized by NMR, UV–Vis spectroscopy, and mass spectrometry.The absorption and emission properties of these new complexes were also examined and compared to those of Co(II), Ni(II), and Pd(II) octabutoxynaphthalocyanines. The results provide useful information to understand the effect of these transition metals on the properties of this macrocyclic ring.
Structure and absorption and emission spectra of Rh-, Ir-, Pd-, and PtNc(OBu)8.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 57, 2 July 2013, Pages 64–69
Journal: Polyhedron - Volume 57, 2 July 2013, Pages 64–69
نویسندگان
Junhwan Kim, Alexandra V. Soldatova, Michael A.J. Rodgers, Malcolm E. Kenney,