Cation-anion interactions involving hydrogen bonds: Syntheses and crystal structures study of hexafluorotitanate(IV) salts with pyridine and methyl substituted pyridines

► Hexafluorotitanate(IV) compounds have been synthesized and characterized. ► Variations in noncovalent interactions have been successfully applied. ► The NMR spectra of compounds in D2O solution were recorded.