کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1338360 | 979664 | 2011 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: New organotin carboxylates derived from 6-chloro-3-pyridineacetic acid exhibiting discrete molecular, drum-like, linear polymeric and ladder structures constructed from dimeric tetraorganodistannoxane units New organotin carboxylates derived from 6-chloro-3-pyridineacetic acid exhibiting discrete molecular, drum-like, linear polymeric and ladder structures constructed from dimeric tetraorganodistannoxane units](/preview/png/1338360.png)
Seven new organotin (IV) carboxylates have been synthesized by the reactions of 6-chloro-3-pyridineacetic acid with triorganotin chloride and diorganotin dichloride. All the complexes were characterized by elemental analysis, IR, 1H NMR, 13C NMR, 119Sn NMR and X-ray crystallography. The structural analyses show that all the complexes present various structures, including monomer, drum, 1D polymers and ladders. It is worth noting that complex 1 is a novel 1D spring-like helical chain containing guest solvent molecules.
Seven new organotin (IV) carboxylates have been synthesized by the reactions of 6-chloro-3-pyridineacetic acid with triorganotin chloride and diorganotin dichloride. All the complexes were characterized by elemental analysis, IR, 1H NMR, 13C NMR, 119Sn NMR and X-ray crystallography. The structural analyses show that the complexes are present as a monomer, a drum, 1D polymers and ladders. It is worth noting that complex 1 is a novel 1D spring-like helical chain containing guest solvent molecules.Figure optionsDownload as PowerPoint slideResearch highlights
► Organotin carboxylates have versatile molecular structures both in the solid state and in solution.
► Seven new organotin (IV) carboxylates have been synthesized by the reactions of 6-chloro-3-pyridineacetic acid with triorganotin chloride and diorganotin dichloride in this paper.
► The organotin structures reported in this paper further enrich organotin chemistry in the structural field.
Journal: Polyhedron - Volume 30, Issue 4, 11 March 2011, Pages 624–631