کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1338434 | 1500284 | 2013 | 11 صفحه PDF | دانلود رایگان |
Reaction of the PhSe− anion with 1,8-bis(2-bromoethoxy)anthracene-9,10-dione, 1,5-bis(2-bromoethoxy)anthracene-9,10-dione, 1,8-bis(2-bromoethylethyleneoxy)anthracene-9,10-dione in 1:1 ratio generates 1,8-bis(2-phenylselenoethoxy)anthracene-9,10-dione (2), 1,5-bis(2-phenylselenoethoxy)anthracene-9,10-dione (3) and 1,8-bis(2-phenylselenoethylethyleneoxy)anthracene-9,10-dione (4). The reaction of 2 with a methanolic solution of Ag(CH3CN)4BF4 and Cu(CH3CN)4BF4, yielded metal complexes 5 and 6, respectively. 3 formed a 1D coordination polymer (7) with Ag(CH3CN)4BF4 in a 1:2 ratio. The anthraquinone in 3 exhibits π–π interactions with distances in a range of 3.512–3.840 Å. 2 acts as a chemodosimeter for Cu2+ and Fe3+ as it undergoes an aryl ether cleavage with Cu2+ and Fe3+, and produces the luminescent 1-hydroxy-8-(2-phenylselenoethoxy)anthracene-9,10-dione (8). Intramolecular hydrogen bonding in 8 is responsible for the red–orange (λmax 595 nm) emission. The X-ray structures of 5, 6, 7, and 8 are reported along with cyclic voltammetric analyses of new organoselenium compounds.
New organoselenoehters containing anthraquinone based open bipodant ligands and Ag(I), Cu(I) complexes have been synthesized and characterized. X-ray structures of complexes shows that the intraannular carbonyl oxygen coordinated with Ag(I). One of the organoselenoether serves as chemodosimeter for Cu2+ and Fe3+. Electrochemical behaviors of new compounds versus Ag/AgCl are also discussed.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 55, 17 May 2013, Pages 144–154