کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1338517 979668 2007 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Conformational study of Co(II), Ni(II), and Cr(III) complexes of the edta-type: Crystal structure of 1D polymeric trans(O6)-Ba[Co(1,3-pddadp)] · 8H2O complex stabilized by infinite water tapes
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Conformational study of Co(II), Ni(II), and Cr(III) complexes of the edta-type: Crystal structure of 1D polymeric trans(O6)-Ba[Co(1,3-pddadp)] · 8H2O complex stabilized by infinite water tapes
چکیده انگلیسی
MM calculations indicate that for the [M(1,3-pddadp)]n− system [where 1,3-pddadp represents the 1,3-propanediamine-N,N′-diacetate-N,N′-di-3-propionate ion, and M = Co(III), Cr(III), Rh(III), Ni(II), and Co(II)], the trans(O5O6) isomer is of the lowest energy. The least energetically favored trans(O)6 [Co(1,3-pddadp)]2− complex anion possesses unusual geometry and conformation of the β-alaninate rings, and forms, in a crystal, polymeric chains glued by infinite water tapes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 26, Issue 13, 6 August 2007, Pages 3437-3447
نویسندگان
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