کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1338724 | 979678 | 2007 | 10 صفحه PDF | دانلود رایگان |

Trying to understand the different recognition factors between thyroxine and its binding proteins, the chemistry of the ternary complexes between copper and o-iodobenzoylglycine (I-hip) [or o-iodobenzoylglycilglycine (BIGG)] as simple thyroxine models were studied with 2,2′-bipyridyl as secondary ligand.Two new compounds have been synthesized and structurally characterized: [Cu(I-hip)(bpy)2]+(I−) · 1.5H2O and [Cu(BIGG)(bpy)2]+(I−) · 4H2O. These compounds and other previously reported by us offer interesting recognition patterns that could have biological relevance: iodine–iodine short interactions, iodine–hydrogen(aliphatic or aromatic) interactions, iodine–metal bonds, iodine–π interactions (like C–H⋯π), and aromatic self-assemblies assisted by iodine atoms. These patterns can be coupled in a synergistic manner, producing, for instance, a new C–I⋯π⋯π⋯I–C cluster pattern.
Trying to understand the different recognition factors between thyroxine and its binding proteins, the chemistry of the ternary complexes between copper and o-iodobenzoylglycine (I-hip) [or o-iodobenzoylglycilglycine (BIGG)] as simple thyroxine models were studied with 2,2′-bipyridyl as secondary ligand.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 26, Issue 7, 1 May 2007, Pages 1417–1426