کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1338837 979682 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, structural characterization and catalytic activity study of Mn(II), Fe(III), Ni(II), Cu(II) and Zn(II) complexes of quinoxaline-2-carboxalidine-2-amino-5-methylphenol: Crystal structure of the nickel(II) complex
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis, structural characterization and catalytic activity study of Mn(II), Fe(III), Ni(II), Cu(II) and Zn(II) complexes of quinoxaline-2-carboxalidine-2-amino-5-methylphenol: Crystal structure of the nickel(II) complex
چکیده انگلیسی

Five new transition metal complexes [MnL(OAc)]·H2O (1), [FeLCl2] (2), [NiL2]·H2O (3), [CuLCl] (4) and [ZnL2]·2H2O (5) have been synthesized using a tridentate Schiff base ligand, HL (quinoxaline-2-carboxalidine-2-amino-5-methylphenol) and the complexes have been characterized by physicochemical and spectroscopic techniques. The spectral analyses reveal an octahedral geometry for 3, square pyramidal structure for 2 and square planar structure for 4. Analytical and physicochemical data indicate tetrahedral structure for 1 and octahedral structure for 5. The crystallographic study reveals that [NiL2]·H2O shows distorted octahedral geometry with a cis arrangement of N4O2 donor set of the bis Schiff base and exhibits a two-dimensional polymeric structure parallel to [0 1 0] plane. The complexes were screened for catalytic phenol hydroxylation reaction. Coordinatively unsaturated manganese(II), iron(III) and copper(II) complexes were found to be active catalysts. The poor catalytic activity of the nickel(II) complex is due to coordinatively saturated octahedral nature of the complex. Maximum conversion of phenol was observed for the copper(II) complex and the major product was catechol.

Five new transition metal complexes [MnL(OAc)]·H2O, [FeLCl2], [NiL2]·H2O, [CuLCl] and [ZnL2]·2H2O have been synthesized and characterized using the ligand, HL (quinoxaline-2-carboxalidine-2-amino-5-methylphenol). The crystallographic study of [NiL2]·H2O reveals a cis arrangement of the bis Schiff base which exhibits a two-dimensional polymeric structure. The complexes were screened for catalytic phenol hydroxylation reaction.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 29, Issue 15, 14 October 2010, Pages 3014–3020
نویسندگان
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