کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1338863 | 979683 | 2007 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and X-ray structures of two discrete metal complexes of 2,2′-bi-1,5-naphthyridine, a new ambivergent ligand Synthesis and X-ray structures of two discrete metal complexes of 2,2′-bi-1,5-naphthyridine, a new ambivergent ligand](/preview/png/1338863.png)
A new synthesis of 2,2′-bi-1,5-naphthyridine (1) is described along with its reactions with copper(II) nitrate, silver(I) tetrafluoroborate and palladium(II) chloride. X-ray crystal structures are described of a mononuclear copper complex, in which 1 acts as a convergent ligand chelating through the two internal nitrogens, and an unusual M4L3 silver complex containing both two- and three-coordinate silvers and with ligand 1 acting in two different bridging modes.
A new synthesis of 2,2′-bi-1,5-naphthyridine (1) is described along with its reactions with copper(II) nitrate, silver(I) tetrafluoroborate and palladium(II) chloride. X-ray crystal structures are described of a mononuclear copper complex, in which 1 acts as a convergent ligand chelating through the two internal nitrogens, and an unusual M4L3 silver complex containing both two- and three-coordinate silvers and with ligand 1 acting in two different bridging modes.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 26, Issue 2, 22 January 2007, Pages 400–405