کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1338910 | 979684 | 2009 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Controlling sequential hydroboration and mechanistic pathway by means of Lewis base/solvent effects: A detailed kinetic and mechanistic study
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
11B NMR spectroscopy was utilized to study hydroboration reactions of 1-octene and 4-octene with H2BCl·THF in THF. The dependence of kobs on the nucleophile concentration and temperature has been investigated. The reactions exhibits simple second-order kinetics of the form kobs=k2â²[Nu]. Based on the activation parameters, it is concluded that hydroboration reactions involving H2BCl·THF in THF proceed through a direct attack mechanism, with the magnitude of the negative values of activation entropy signifying a compact transition state i.e. a limiting associative pathway (A). The increase in the steric strain due to the compact nature of the transition state resulted in the rate of the second step of hydroboration of 4-octene being slightly higher than that of 1-octene.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 28, Issue 18, 8 December 2009, Pages 4110-4114
Journal: Polyhedron - Volume 28, Issue 18, 8 December 2009, Pages 4110-4114
نویسندگان
N. Xaba, D. Jaganyi,