Template synthesis and characterization of host (nanopores of zeolite Y)/guest (Co(II)-tetraoxodithiatetraaza macrocyclic complexes) nanocomposite materials

A series of Co(II) tetraoxodithiatetraaza macrocyclic complexes ([18]aneN4S2, [20]aneN4S2, Bzo2[18]aneN4S2 and Bzo2[20]aneN4S2) have been encapsulated in the nanopores of zeolite Y by template condensation reaction. Co(II) complexes with tetraoxodithiatetraaza macrocyclic ligand were entrapped in the nanopores of zeolite Y by a two-steps process in the liquid phase: (i) ion-exchange of [bis(diamine)cobalt(II)] (diamine = 1,2-diaminoethane, 1,3-diaminopropane, 1,2-diaminobenzene, 1,3-diaminobenzene); [Co(N–N)2]2+–NaY; in the nano-cavity of the zeolite, and (ii) in situ template condensation of the cobalt(II) precursor complex with thiodiglycolic acid. The mode of bonding and overall geometry of the complexes and new host/guest nanocomposite materials ([Co([18]aneN4S2)]2+–NaY, [Co([20]aneN4S2)]2+–NaY, [Co(Bzo2[18]aneN4S2)]2+–NaY, [Co(Bzo2[20]aneN4S2)2+–NaY) has been inferred through FT-IR, DRS and UV–Vis spectroscopic techniques, BET technique, molar conductance and magnetic moment data, XRD and elemental analysis, as well as nitrogen adsorption. The average number of encapsulated Co complexes per nano-cavity was determined to be 0.33 for the Co complexes–NaY. An octahedral geometry around the cobalt(II) ion is suggested for the complexes and new host/guest nanocomposite materials.

graphical abstractA series of Co(II) tetraoxodithiatetraaza macrocyclic complexes ([18]aneN4S2, [20]aneN4S2, Bzo2[18]aneN4S2 and Bzo2[20]aneN4S2) have been encapsulated in the nanopores of zeolite Y by template condensation reaction. Co(II) complexes with tetraoxodithiatetraaza macrocyclic ligand were entrapped in the nanopores of zeolite Y by a two-steps process in the liquid phase: (i) adsorption of [bis(diamine)cobalt(II)] (diamine = 1,2-diaminoethane, 1,3-diaminopropane, 1,2-diaminobenzene, 1,3-diaminobenzene); [Co(N-N)2]2+-NaY; in the supercages of the zeolite, and (ii) in situ template condensation of the cobalt(II) precursor complex with thiodiglycolic acid.Figure optionsDownload as PowerPoint slide