کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1339172 | 979697 | 2010 | 13 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Influence of the nature of organic components in dinuclear copper(II) pivalates on the composition of thermal decomposition products Influence of the nature of organic components in dinuclear copper(II) pivalates on the composition of thermal decomposition products](/preview/png/1339172.png)
Tetrabridged dinuclear complexes ((2-NH2)C5H4N)2Cu2(μ2-OOCCMe3)4 (2·С6Н6) and ((3-NH2)C5H4N)2Cu2(μ2-OOCCMe3)4 (3) and the cocrystallization product ((4-NMe2)C5H4N)2Cu(η2–OOCCMe3)2·2((4-NMe2)C5H4N)2Cu2(μ2-OOCCMe3)4 (4) were synthesized by the reaction of the polymer [Cu(OOCCMe3)2]n (1) with aminopyridine ligands (L) of different nature (Cu: L = 1:1) in С6Н6. The solid-state thermal decomposition of these compounds was studied by differential scanning calorimetry and thermogravimetry, and their electrochemical behavior was investigated by cyclic voltammetry. All newly synthesized complexes were studied by X-ray diffraction, the magnetic properties of the complexes were investigated, and ESR measurements were performed.
New dinuclear complexes ((2-NH2)C5H4N)2Cu2(μ2-OOCCMe3)4·С6Н6 and ((3-NH2)C5H4N)2Cu2(μ2-OOCCMe3)4 and the co-crystallization product ((4-NMe2)C5H4N)2Cu(η2–OOCCMe3)2·2((4-NMe2)C5H4N)2Cu2(μ2-OOCCMe3)4 were synthesized. These complexes were studied by X-ray diffraction. The magnetic properties, the solid-state thermal decomposition and the electrochemical behavior were investigated.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 29, Issue 7, 10 May 2010, Pages 1734–1746