کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1339209 | 979698 | 2006 | 13 صفحه PDF | دانلود رایگان |
The syntheses and characterization of six ditopic ligands which contain polyethyleneoxy-substituted naphthalene spacers connecting two 2,2′:6′,2″-terpyridine metal-binding domains are described. The ligands, L, have been used to prepare two series of ruthenium(II) complexes: linear complexes of type [(tpy)Ru(L)Ru(tpy)]4+ were prepared as models for polymeric species, and metallomacrocyclic species [RunLn]2n+ (n = 2 or 3). Single crystal structures of a representative ligand and macrocyclic Ru(II) complex are reported.
The syntheses and characterization of six ligands (L) with polyethyleneoxy-substituted naphthalene spacers connecting two 2,2′:6′,2″-terpyridine metal-binding domains are described, along with linear complexes [(tpy)Ru(L)Ru(tpy)]4+ and metallomacrocyclic species [RunLn]2n+ (n = 2 or 3).Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 25, Issue 8, 29 May 2006, Pages 1831–1843