کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1339215 1500293 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, crystal structure and electrochemistry of a ruthenium complex coordinated with an ambidentate 2-mercaptopyridinato N-oxide ligand
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis, crystal structure and electrochemistry of a ruthenium complex coordinated with an ambidentate 2-mercaptopyridinato N-oxide ligand
چکیده انگلیسی

A polypyridyl ruthenium complex monodentately coordinated by 2-mercaptopyridine N-oxide was prepared as a candidate for showing linkage isomerisation. [Ru(bpy)(tpy)(2-OpyS)]PF6 (bpy: 2,2′-bipyridine; tpy: 2,2′:6′,2″-terpyridine; 2-OpyS−: anion of 2-mercaptopyridine N-oxide) was synthesised and structurally characterised. The complex contains a 2-OpyS− ligand coordinating only with the sulphur atom. Electrochemically induced linkage isomerisation was examined for this complex.

[Ru(2,2′-bipyridine)(2,2′:6′,2″-terpyridine)(2-mercaptopyridinato N-oxide)]PF6 was synthesized, structurally characterized, and electrochemically investigated. This is a novel example of a ruthenium complex in which the 2-mercaptopyridinato N-oxide ligand coordinates to ruthenium only through sulphur.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 27, Issues 9–10, 26 June 2008, Pages 2031–2034
نویسندگان
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