کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1339516 979707 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Modulation of intermolecular exchange interaction in organic radical based compounds: Magneto-structural analysis of phenol and imidazolium substituted oxoverdazyl radicals
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Modulation of intermolecular exchange interaction in organic radical based compounds: Magneto-structural analysis of phenol and imidazolium substituted oxoverdazyl radicals
چکیده انگلیسی

The synthesis of two oxoverdazyls based compounds, the 1,5-dimethyl-3-(2′-hydroxyphenyl)-6-oxoverdazyl 1 and the perchlorate salt of 1,5-dimethyl-3-(2′-imidazolium)-6-oxoverdazyl 2 are reported. The structural analysis of 1 reveals that radicals are closely packed in regular columns by way of π-stacking. In contrast, the packing in 2 is definitely influenced by the protonation state of the radical substituent and shows strong lateral staggering of the organic radicals. The organisation in the solid state strongly influences the intermolecular exchange interaction between π-stacked radicals which goes from J = −113 cm−1 (H = −J∑SiSi+1) in 1 to J = −1.0 cm−1 and J′ = −0.67 cm−1 in 2.

The crystal packing of two oxoverdazyl radicals is so different that the intermolecular exchange interaction between the radical varies by two orders of magnitude.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 29, Issue 1, 13 January 2010, Pages 342–348
نویسندگان
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