کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1339848 | 979715 | 2007 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Reduction-induced o-C–H bond activation of pyridine with decamethylzirconocene dichloride Reduction-induced o-C–H bond activation of pyridine with decamethylzirconocene dichloride](/preview/png/1339848.png)
Treatment of decamethylzirconocene dichloride (η5-Cp∗)2ZrCl2 with amalgamated magnesium in pyridine results in formation of the o-C–H bond activation product [η5-C5Me5]2ZrH[η2-κC,N-C5H4N] (1). X-ray diffraction analysis (solid state) and NMR spectroscopy data (solutions) reveal the lateral positioning of the nitrogen atom in 1. At elevated temperatures, complex 1 smoothly rearranges into its isomer 2 with medial positioning of the N-atom. The parameters of equilibrium between 1 and 2 were measured at different temperatures. A reaction of 1 or a mixture of 1 and 2 (ca. 1:10) with CDCl3 smoothly and under mild conditions leads to one and the same η2-pyridyl chloride complex [η5-C5Me5]2ZrCl[η2-κC,N-C5H4N] (3) with medial positioning of the N-atom. The thermodynamic and mechanistic concepts of the paper are discussed with application of the DFT computational data.
Treatment of decamethylzirconocene dichloride (η5-Cp∗)2ZrCl2 with amalgamated magnesium in pyridine results in the formation of the o-C–H bond activation product [η5-C5Me5]2ZrH[η2-κC,N-C5H4N] with the lateral positioning of the nitrogen atom. At elevated temperatures, this complex smoothly rearranges into its isomer with a medial positioning of the N-atom.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 26, Issue 12, 23 July 2007, Pages 2864–2870