کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1339854 | 979715 | 2007 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Re(I)(tricarbonyl)(carboxylate) complexes with the [N,Nâ²-bis(2,4,6-trimethylbenzene)-1,4-diazabutadiene] (2,4,6-Me3G) and [N,Nâ²-bis(2,4-dimethylbenzene)-2,3-dimethyl-1,4-diazabutadiene] (2,4-Me2D) ligands - Syntheses and spectroscopic studies. The cry
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Two new carboxylato complexes, [Re(CO)3(DAB)(OCOCF3)] (DABÂ =Â substituted diazabutadiene ligands), were prepared by the reaction of [Re(CO)5Cl] with the DAB ligands, and the subsequent reaction with AgOCOCF3 gave the related carboxylate complexes. Their pseudooctahedral fac structure has been established by FTIR, UV-Vis and NMR spectroscopies, and has been confirmed by X-ray diffraction analysis. Electrochemical behaviour of the investigated complexes has been studied by cyclic voltammetry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 26, Issue 12, 23 July 2007, Pages 2906-2910
Journal: Polyhedron - Volume 26, Issue 12, 23 July 2007, Pages 2906-2910
نویسندگان
Reza Kia, Valiollah Mirkhani, Alajos Kálmán, Andrea Deák,