کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1339898 | 1500292 | 2009 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and physical properties of a new single-component molecular conductor [Au(dhdt)2]
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and physical properties of a new single-component molecular conductor [Au(dhdt)2] Synthesis and physical properties of a new single-component molecular conductor [Au(dhdt)2]](/preview/png/1339898.png)
چکیده انگلیسی
New Au(III) complexes coordinated by Ï-reduced TTF-type ligands were prepared and crystal structure of the tetraphenylphosphonium salt was clarified. A neutral complex [Au(dhdt)2] was obtained by the electrochemical oxidation of (n-Bu4N)[Au(dhdt)2]. Conducting behavior of [Au(dhdt)2] was semiconductive with conductivity at room temperature of 8.3Â Scmâ1, indicating the neutral complex [Au(dhdt)2] is a single-component conductor. Magnetic susceptibility of [Au(dhdt)2] was well explained by the sum of the Curie and temperature independent components.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 28, Issues 9â10, 22 June 2009, Pages 1634-1637
Journal: Polyhedron - Volume 28, Issues 9â10, 22 June 2009, Pages 1634-1637
نویسندگان
Hiroyuki Nishikawa, Wataru Yasuoka, Kumiko Sakairi, Hiroki Oshio,