کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1340054 | 1500294 | 2007 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: m-Phenylenediamine-based high-spin dication diradicals: Analysis of the decomposed products m-Phenylenediamine-based high-spin dication diradicals: Analysis of the decomposed products](/preview/png/1340054.png)
A tetraaryl-m-phenylenediamine dication diradical in the triplet ground state was chemically generated and decomposed in preparative scale. The obtained mixture was separated and purified to examine the decomposed products. A nitro compound and a biaryl were formed as the main products, indicating the cleavage of the pi-conjugation. The relationship between the substituent influence and the structure of the decomposed products, and reaction mechanism are reported. These results serve for establishing guidelines for molecular designing of next-generation charged high-spin molecular systems such as oligoarylamine-based pluri-charged high-spin molecules, in a more sophisticated manner.
A tetraaryl-m-phenylenediamine dication diradical, which exhibits ground-state triplet, was chemically generated and decomposed in preparative scale. A nitro compound and a biaryl were formed as main products, indicating the cleavage of pi-system.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 26, Issues 9–11, 15 June 2007, Pages 2027–2030