کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1340472 | 979737 | 2008 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis, characterization and crystal structure of new silver(I) and palladium(II) complexes containing 1,2,4-triazole moieties Synthesis, characterization and crystal structure of new silver(I) and palladium(II) complexes containing 1,2,4-triazole moieties](/preview/png/1340472.png)
The reaction of 4-amino-5-ethyl-2H-1,2,4-triazole-3(4H)-thione (AETT, L1) with 2-thiophen carbaldehyde in methanol leads to the corresponding Schiff-base HL1a. The reaction of L1 with AgNO3 in ethanol gives the ionic complex [{[Ag(L1)]NO3}2]n (1). The ionic complex [(PPh3)2Ag(HL1a)2]NO3 · CH3CN (2) can be obtained by the reaction of HL1a with [(PPh3)2Ag]NO3 in methanol and acetonitrile solution, while its reaction with [(PPh3)2PdCl2] in the presence of sodium acetate in methanol leads to the neutral complex [(PPh3)2Pd(L1a)2] · 4MeOH (3). All the compounds were characterized by infrared spectroscopy, elemental analyses as well as by X-ray diffraction studies.
The reaction of 4-amino-5-ethyl-2H-1,2,4-triazole-3(4H)-thione (AETT) with AgNO3 in ethanol gave the ionic complex [{[Ag(AETT)]NO3}2]n with an interesting 10-membered silver–sulfur “mosaic” pattern. The behavior of Schiff-bases derived from AETT towards silver(I) and palladium(II) was also studied.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 27, Issue 6, 25 April 2008, Pages 1655–1664