Three interpenetrated frameworks constructed by long flexible N,N′-bipyridyl and dicarboxylate ligands

Three interpenetrated polymeric networks, {[Co(bpp)(OH-BDC)] · H2O}n (1) [Ni(bpp)1.5(H2O)(OH-BDC)]n (2) and {[Cd(bpp)(H2O)(OH-BDC)] · 2H2O}n (3), have been prepared by hydrothermal reactions of 1,3-bis(4-pyridyl)propane (bpp), 5-hydroxyisophthalic acid (OH-H2BDC), with Co(NO3)2 · 6H2O, Ni(NO3)2 · 6H2O and Cd(NO3)2 · 4H2O, respectively. Single-crystal X-ray diffraction analyses reveal that the three compounds all exhibit interpenetrated but entirely different structures. Compound 1 is a fourfold interpenetrated adamantanoid structure with water molecules as space fillers, in which bpp adopts a TG conformation (T = trans, G = gauche). Compound 2 is an interdigitated structure from the interpenetrated long arms of one-dimensional molecular ladders, while bpp in 2 adopts both TT and TG conformations. Compound 3 is a twofold interpenetrated three-dimensional network from a one-dimensional metal-carboxylate chain bridged by TG conformational bpp. The hydrogen bonding interactions in 1–3 further stabilize the whole structural frameworks and play critical roles in their constructions.

The hydrothermal reactions of 1,3-bis(4-pyridyl)propane (bpp), 5-hydroxyisophthalic acid (OH-H2BDC) and different metal ions gave rise to three coordination polymers, {[Co(bpp)(OH-BDC)] · H2O}n (1) [Ni(bpp)1.5(H2O)(OH-BDC)]n (2) and {[Cd(bpp)(H2O)(OH-BDC)] · 2H2O}n (3). The long flexible bpp ligands adopt different conformations to take part in coordination in the three compounds.Figure optionsDownload as PowerPoint slide