کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1341164 | 979777 | 2005 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis, characterization and molecular structure of [1-HOCPh2-2-NHMe2C6H4][MeSO3] · MeSO3H Synthesis, characterization and molecular structure of [1-HOCPh2-2-NHMe2C6H4][MeSO3] · MeSO3H](/preview/png/1341164.png)
BEt2(OSO2CH3) was treated with 1-HOCPh2-2-NMe2C6H4 (1) in the presence of acetic acid to give a red oily residue, which was separated by column chromatography into the two products [1-HOCPh2-2-NHMe2C6H4][MeSO3] · MeSO3H (2) and the known compound (BEt)2(μ-O)(μ-O,O′-O2CCH3)2 (3). Compound 2 was prepared independently from 1 and methylsulfonic acid. Compound 2 was characterized spectroscopically (NMR, IR) and by crystal structure determination. The latter shows the association of two ions and one molecule [1-HOCPh2-2-NHMe2C6H4]+, [MeSO3]− and MeSO3H by hydrogen bonding.
[1-HOCPh2-2-NHMe2C6H4][MeSO3] · MeSO3H (2) was prepared from 1-HOCPh2-2-NMe2C6H4 and methylsulfonic acid and was characterized spectroscopically (NMR, IR) and by crystal structure determination. The latter shows the association of two ions [1-HOCPh2-2-NHMe2C6H4]+ and [MeSO3]− and one molecule MeSO3H by hydrogen bonding.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 24, Issue 15, 27 October 2005, Pages 1937–1940