کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1440101 | 1509357 | 2016 | 9 صفحه PDF | دانلود رایگان |
• The core-shell structure of Ni@SnO2@PPy was synthesized via a three-step method.
• The composite has a ferromagnetic behavior.
• The maximum reflection loss of Ni@SnO2@PPy composite can reach −30.1 dB at 5.6 GHz with a coating layer thickness of 3.5 mm.
• The absorption bandwidth exceeding −10 dB is almost up to 7.4 GHz (from 3.7 to 6.8 GHz, from 13.7 to 18 GHz).
A ternary composite of Ni@SnO2@PPy was synthesized via a three-step method, a facile hydrothermal route (Ni) in first step and (Ni@SnO2) in second step and followed by the in situ polymerization of PPy on the surface of Ni@SnO2. The obtained ternary composite was characterized by various instruments and the TEM analysis indicated that Ni particles were homogenously enwrapped by SnO2 and PPy. The Ni particles with a size of about 200–500 nm are core, SnO2 and PPy form shell. The electromagnetic properties of the core-shell structured Ni@SnO2@PPy (−30.1 dB) are much better than Ni (−10.75 dB) and Ni@SnO2 (−13.8 dB), which is mainly attributed to the improved impedance matching and enhanced interfacial effects. The maximum reflection loss of Ni@SnO2@PPy can reach −30.1 dB at 5.6 GHz and the absorption bandwidth with the reflection loss below −10 dB is 7.4 GHz (from 3.7 to 6.8 GHz, from 13.7 to 18 GHz) with the thickness of 3.5 mm. Our results indicate that the Ni@SnO2@PPy composite is a promising microwave absorbent with thin thickness, strong absorption, and broad bandwidth.
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Journal: Synthetic Metals - Volume 220, October 2016, Pages 347–355