کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1440177 1509360 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Carbazole-substituted metallo-phthalocyanines: Synthesis, electrochemical, and spectroelectrochemical properties
ترجمه فارسی عنوان
متال فتالوسیانینهاى کربازولى: سنتز، خواص الکتریکى و خواص اسپکترومغناطیسی
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد بیومتریال
چکیده انگلیسی


• New Pcs with four 9H-carbazole-9-ethoxy groups have been prepared.
• Aggregation tendency vs. concentration has been tested.
• Electrochemical and spectroelectrochemical characterization of MPcs were performed.

The syntheses of tetrasubstituted metallo-phthalocyanines (cobalt, zinc, and manganese) bearing four 9H-carbazole-9-ethoxy units have been reported. All of the synthesised compounds have been characterised by using FT-IR, UV–vis, 1H NMR, and MALDI-TOF/MS spectroscopic data. The aggregation behaviours of the newly synthesised compounds were investigated in different concentrations. Electrochemical and spectroelectrochemical characterisation of Cl-MnPc was performed in DMF. Two metal-based reductions followed a Pc ring-based reduction. An irreversible Pc ring-based oxidation could only be detected with square wave voltammetry. In situ spectroelectrochemical and electrocolorimetric measurements were performed in order to determine the colours and spectra of the electrogenerated species of the complex.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Synthetic Metals - Volume 217, July 2016, Pages 94–101
نویسندگان
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