Synthesis and microstructural characterization of Al–Ni3Al composites fabricated by press-sintering and shock-compaction

• Nanocrystalline Ni3Al was obtained by mechanical alloying with 5 nm grain size.
• The Ni3Al particles are homogeneously distributed on the matrix.
• Nanoscale features of Ni3Al were retained after compaction process.
• The highest hardness was obtained for the Al–4 vol.%Ni3Al shock-compacted composite.

Aluminum matrix composites reinforced with nanocrystalline Ni3Al intermetallic particles, were synthesized using powder metallurgy techniques. Nanocrystalline Ni3Al was obtained by mechanical alloying of Ni75–Al25 stoichiometric mixture from elemental powders after 900 ks of milling with a 5 nm grain size average. Mixture powders of aluminum with 0.007, 0.02 and 0.04 volume fractions of Ni3Al intermetallic particles were compacted using two different compaction methods, the cold isostatic press and sintered at 873 K and the shock-compaction technique. Microstructure of shock-compacted composites showed fine particles of a few microns and also coarse particles less than 100 μm homogeneously distributed on the matrix, also the presence of micro-cracks and low porosity. However the nanoscale features of intermetallic was retained. On the other hand, the press and sintered composites showed good densification. The densities of the composites were about 90% and 94% of the theoretical density for the shock-compacted and press-sintered process, respectively. Finally, the results of hardness measurements showed that the nanocrystalline Ni3Al reinforcement improves the hardness of Al matrix for all conditions. The highest hardness was obtained for the Al–4 vol.%Ni3Al shock-compacted composite.

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