کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1440683 | 1509375 | 2015 | 8 صفحه PDF | دانلود رایگان |
• Chiral inducers were synthesized from l-borneol.
• Helical twisting power depends on molecular geometry of the chiral inducers.
• CD intensity of the PEDOT films depends on HTP of the chiral inducers.
• The PEDOT film (PF-para) is electro-chiroptically active.
Five chiral inducers were synthesized with l-borneol and benzenecarboxylic acids. These chiral inducers have the same substituent (bornyl ester) but different geometries. Para-substituted chiral inducer (I-p) shows relatively high macroscopic helical twisting power (βM), while ortho-substituted chiral inducer (I-o) shows lower. This difference is related with the geometric similarity between the chiral inducers and the host liquid crystals. The result also suggested that distortion of π system induced by polar solvents causes low βM of the I-o. Optically active poly(3,4-ethylenedioxythiophene) (PEDOT) films were chemically prepared in cholesteric liquid crystal (CLC) electrolyte solution induced by the chiral inducers. Circular dichroism (CD) intensities of the resultant polymer films are almost proportional to helical twisting power (HTP) of the chiral inducers. Optical rotatory dispersion (ORD) spectra of the polymer film prepared in the CLC electrolyte induced by I-p (PF-para) shows isosbestic point during the oxidation. This indicates that electro-chiroptically active polymer film was obtained through chiral induction of the bornyl chiral inducer.
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Journal: Synthetic Metals - Volume 202, April 2015, Pages 157–164