کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1440765 | 1509378 | 2015 | 6 صفحه PDF | دانلود رایگان |
• A new donor–acceptor type green fluorescent emitter, PhBBPP, was synthesized.
• Thermal, photophysical, and electrochemical properties of PhBBPP were investigated.
• PhBBPP showed high thermal stability and efficient intramolecular charge transfer.
• A high luminous efficiency of 12.1 cd/A was achieved in non-doped OLED.
We synthesized a new donor–acceptor type (D–A type) green fluorescent emitter, 3,7-bis(1-(biphenyl-4-yl)-1H-benzo[d]imidazole-2-yl)-10-phenyl-10H-phenothiazine (PhBBPP), which consists of phenylphenothiazine as an electron donor and biphenylbenzimidazole as an acceptor. Its thermal and photophysical properties, and energy band structure were studied, and also organic light-emitting diodes (OLEDs) with various device structures were fabricated using PhBBPP as an emitting layer. The optimized OLED device with a structure of [ITO/NPB (40 nm)/PhBBPP (30 nm)/TPBi (30 nm)/Alq3 (10 nm)/LiF (1 nm)/Al (100 nm)] showed a turn-on voltage of 3.4 V, a luminous efficiency of 12.1 cd/A, and an external quantum efficiency of 4.0% at 100 cd/m2 with a maximum luminance of 8200 cd/m2.
Figure optionsDownload as PowerPoint slide
Journal: Synthetic Metals - Volume 199, January 2015, Pages 8–13