کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1441212 | 1509395 | 2013 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Non-covalently functionalized single walled carbon nanotube/poly(3,4ethylenedioxythiophene):poly(styrenesulfonate) nanocomposites for organic photovoltaic cell Non-covalently functionalized single walled carbon nanotube/poly(3,4ethylenedioxythiophene):poly(styrenesulfonate) nanocomposites for organic photovoltaic cell](/preview/png/1441212.png)
• We fabricated SWNT/PEDOT:PSS nanocomposites by using non-covalently functionalized SWNTs.
• Non-covalently functionalized SWNT/PEDOT:PSS showed higher electrical conductivity.
• Non-covalently functionalized SWNT/PEDOT:PSS was applied in OPVC as hole transport layer.
• OPVC with non-covalently functionalized SWNT/PEDOT:PSS resulted in an increase of PCE.
In this study, we developed a non-covalent functionalization method to disperse single walled CNTs (SWNTs) with minimal loss of electrical properties. SWNTs were non-covalently functionalized by 1-aminopyrene (AP-SWNTs), and covalently functionalized SWNTs (carboxylate-SWNTs) were fabricated by strong acid treatment for comparing the properties of functionalized SWNTs. By using functionalized SWNTs, SWNT/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) nanocomposites were fabricated as transparent conductive films. AP-SWNT/PEDOT:PSS nanocomposites showed higher electrical conductivity (sheet resistance: 634 Ω/sq) at a similar optical transmittance compared to raw PEDOT:PSS (1555 Ω/sq) and carboxylate SWNT/PEDOT:PSS nanocomposites (933 Ω/sq) due to homogeneously dispersed AP-SWNTs in matrix with minimal damages during the functionalization. We also applied the AP-SWNT/PEDOT:PSS nanocomposites as a hole conducting layer in an organic photovoltaic cell (OPVC) application. Power conversion efficiency (PCE) of the OPVC using AP-SWNT/PEDOT:PSS was enhanced from 2.3% to 3.0% compared to an OPVC using raw PEDOT:PSS. The main reason for this enhancement of the PCE was thought to be the increase of JSC due to effective hole transport and collection by highly conductive, AP-SWNT/PEDOT:PSS nanocomposites.
Journal: Synthetic Metals - Volume 181, 1 October 2013, Pages 92–97