A thermally stable bipolar host material for blue phosphorescent organic light-emitting diodes

• Thermally stable bipolar host material up to 130 °C.
• High quantum efficiency in blue phosphorescent organic light-emitting diodes.
• Dibenzofuran based high triplet energy host material.

A dibenzofuran based host material, 9,9′-(4-(diphenylphosphoryl)dibenzo[b,d]furan-2,8-diyl)bis(9H-carbazole) (DBFDCzPO), was developed as a thermally stable high triplet energy host material for blue phosphorescent organic light-emitting diodes (PHOLEDs). DBFDCzPO showed high triplet energy of 2.89 eV and stable film morphology up to 130 °C. DBFDCzPO was compared 2,8-di(9H-carbazol-9-yl)dibenzo[b,d]furan and exhibited better device performances. A high quantum efficiency of 17.6% was achieved in the blue PHOLEDs using the DBFDCzPO host material.

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