کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1441632 | 1509419 | 2012 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: One-step chemical vapor synthesis of Ni/graphene nanocomposites with excellent electromagnetic and electrocatalytic properties One-step chemical vapor synthesis of Ni/graphene nanocomposites with excellent electromagnetic and electrocatalytic properties](/preview/png/1441632.png)
We present the first report concerning the one-step synthesis of Ni/graphene nanocomposites via a substrate-free, atmospheric-pressure chemical vapor deposition process. The as-grown thin graphene sheets are produced in large scale with the thickness of ∼2 nm, and they are decorated with numerous Ni/graphene core–shell nanoparticles. The nucleation and growth mechanism of the composite has been proposed based on careful transmission electron microscopy analysis. Ni3C domains within Ni nanoparticles have been observed, indicating a transformation between nickel and nickel carbide during graphene growth owing to the diffuse and precipitation of carbon atoms. Moreover, such Ni/graphene nanocomposites exhibit excellent microwave absorption and electrochemical ethanol sensing properties. This study opens up a new synthesis route for graphene-based materials.
Journal: Synthetic Metals - Volume 162, Issues 11–12, July 2012, Pages 968–973