کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1441972 | 1509429 | 2011 | 11 صفحه PDF | دانلود رایگان |
We have synthesized and characterized donor–π–spacer–acceptor type molecules in which 1,3,4-oxadiazoles are π-spacers, triphenylamines are the donors and cyanoacetic acid are the acceptors for use as sensitizers in dye-sensitized solar cells (DSSCs). Detailed absorption, emission, electrochemical, photoelectrochemical and computational studies have been carried out on five novel derivatives. The dyes have an absorption range of 377–388 nm, and an emission in the range of 494–540 nm. There is a large charge transfer from the donor side to the acceptor side on excitation. The propeller shape of the triphenylamine and the bulky substituents on it help in reducing the dye-aggregation on TiO2 surface. The dyes exhibited good overall conversion efficiency (2.79–3.21%). Plane wave calculations indicate that the dye has a reasonably strong binding to the TiO2 surface and the generated DOS picture shows an overlap of the molecular orbitals of the dye and the TiO2 bands. We conclude that the dyes have a promising role as sensitizers in DSSC.
► Here we report efficient synthesis and characterization of new series of Triarylamine linked 1,3,4-oxadiazoles derivatives as sensitizers in DSSCs.
► The dye-based devices exhibited good IPCEs, ranging from 60%to 70%.
► The device using M4 (3.21%) has the best efficiency which reached ∼50% of an N719-based DSSC (6.31%).
► The efficiencies are enhanced due to the non-aggregation of the bulky molecules on the TiO2 surface.
Journal: Synthetic Metals - Volume 161, Issues 15–16, August 2011, Pages 1671–1681