کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1442396 | 1509441 | 2010 | 7 صفحه PDF | دانلود رایگان |
New type of alternating fluorene-based copolymers containing electron-deficient aryl-substituted imidazole units in the main chains were designed, synthesized and characterized. The resulting copolymers were amorphous and showed excellent solubility in common organic solvents, such as dichloromethane, chloroform, 1,2-dichloroethane, chlorobenzene, toluene, and THF. These polymers also possessed good thermal stability with glass transition temperatures of 96 and 82 °C and decomposition onset temperatures of 365 and 379 °C, respectively. They exhibited good blue photoluminescence properties with high photoluminescence efficiencies. The long-wavelength emission of polyfluorenes had been effectively reduced by introduction of nonlinear structure aryl-substituted imidazole units. Light-emitting devices with an ITO/PEDOT/PVK/copolymer/LiF/Al configuration could emit strong blue light with high external quantum efficiencies of 1.49 and 2.05%.
New type of fluorene-based copolymers containing electron-deficient aryl-substituted imidazole units were successfully synthesized and characterized. The resulting copolymers have good thermal stability, improved electron affinity and high PL efficiencies. The long-wavelength emission of polyfluorenes had been effectively reduced in these copolymers. Light-emitting devices based on these copolymers could emit strong blue light with high external quantum efficiencies of 1.49 and 2.05%, indicating these copolymers are promising candidates for efficient light-emitting materials.Figure optionsDownload as PowerPoint slide
Journal: Synthetic Metals - Volume 160, Issues 15–16, August 2010, Pages 1672–1678