کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1442856 | 1509450 | 2009 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
An in situ Raman spectroelectrochemical study of the controlled doping of semiconducting single walled carbon nanotubes in a conducting polymer matrix
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
بیومتریال
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
The interaction of semiconducting single wall carbon nanotubes (SWCNT) and the conducting polymer poly(3,4-ethylendioxythiophene/polystyrenesulfonate) (PEDOT/PSS) was studied by Raman spectroscopy and in-situ Raman spectroelectrochemistry. The mixing of SWCNT with PEDOT/PSS caused a partial doping of SWCNT as indicated by the change of the relative intensity of the Raman features of SWCNT. The in situ Raman spectroelectrochemical measurements showed that semiconducting tubes could be doped even if they are embedded in PEDOT/PSS. However, in contrast to the neat SWCNT, the doping of SWCNT in composite is less efficient. For SWCNT in composite it is necessary to apply larger potential (by about 0.4-0.6Â V) to achieve the same level of bleaching of Raman bands as in the case of neat SWCNT.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Synthetic Metals - Volume 159, Issues 21â22, November 2009, Pages 2245-2248
Journal: Synthetic Metals - Volume 159, Issues 21â22, November 2009, Pages 2245-2248
نویسندگان
Martin KalbáÄ, Ladislav Kavan, Lothar Dunsch,