Synthesis and characterization of anatase photocatalyst powder from sodium titanate compounds

The synthesis of anatase photocatalyst powder from sodium titanate compounds prepared from rutile and sodium carbonate powder was studied. The sodium titanate compounds were derived from the solid-state reactions of three different (1:4, 1:1.58 and 1:0.73) (m/m) ratios of TiO2:Na2CO3 at 850 °C. Then, the powder was dissolved in 5 M H2SO4 solution, filtered, washed, dried and calcined at 400, 500 or 600 °C for 2 h. The effects of processing parameters on the resultant phase structure, crystallite size, morphology and the surface area of the synthesized powders were investigated. It was found that the anatase powder with a crystallite size of about 102 nm and a specific surface area of 16.7 m2/g synthesized from sodium titanate compounds with a 1:1.58 (m/m) ratio of TiO2:Na2CO3 and calcined at 600 °C showed the best photocatalytic activity to degrade of methylene blue in aqueous solution under UV irradiation.

TiO2 (anatase) powder synthesized from Na8Ti5O14 produced by the solid-state reaction between TiO2 (rutile) and Na2CO3 after dissolving in H2SO4 solution, and calcining at 400 °C for 2 h.Figure optionsDownload as PowerPoint slideHighlights
► We report the synthesis of TiO2 photocatalyst powder from sodium titanate compound.
► The sodium titanate compound was produced by the solid-state reaction between rutile and sodium carbonate.
► High photocatalytic TiO2 could be produced from purified rutile powder.