کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1443057 1509454 2009 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of π-conjugated copolymer with dibenzo[d,d′]benzo[1,2-b:4,5-b′]difuran unit in the main chain
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد بیومتریال
پیش نمایش صفحه اول مقاله
Synthesis of π-conjugated copolymer with dibenzo[d,d′]benzo[1,2-b:4,5-b′]difuran unit in the main chain
چکیده انگلیسی

New π-conjugated polymers with dibenzo[d,d′]benzo[1,2-b:4,5-b′]difuran (DBBDF) unit in the main chains were synthesized. Copolymerization of 6,12-diiodo-DBBDF with p-diethynylbenzene or 2,7-diethynylfluorene derivative under Sonogashira–Hagiwara coupling-reaction condition gave the corresponding copolymer. The resulting copolymers were soluble in organic solvents such as tetrahydrofuran and chloroform. In UV–vis absorption spectra, both copolymers showed red-shifted spectra compared to their monomer units. In the chloroform solutions, the copolymer with DBBDF and p-diethynylbenzene units showed yellowish-green emission, while the copolymer with DBBDF and 2,7-diethynylfluorene units did greenish-blue emission.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Synthetic Metals - Volume 159, Issues 9–10, May 2009, Pages 939–942
نویسندگان
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